Turkish coal is generally poor quality and the levels of chemical and radiological toxic trace elements in it are higher with respect to mean values of activity concentrations given in United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) Report. The main pathways through which the population living around soal-fired power plant (CFPP) is exposed to natural radionuclides are external and internal (ingestion and inhalation) dose and fly ash particles are the major component of the risk. It is estimated that the people working or living near the CFPP in Turkey receive a dose in between 0.1 mSv to 1 mSv extra from CFPP because nearly all the region of Turkey uranium (U) and thorium (Th) content in the coal are higher than 5 ppm to 7 ppm and around 25 ppm to 40 ppm respectively. Continuous monitoring is essential to determine occupational exposure levels in all stages of the coal fuel-cycle and proper measures should be taken to prevent direct contact of the ash pile with the top soil and local drainage systems.