Phenol and its derivatives are considered detrimental to environment and need to be removed from environ- ment. Enzymatic oxidation of chlorophenols is considered as viable option but leads to precipitate due to polymerization of phenolic compounds, which require additional step of flocculation towards safe discarding of contaminated waters. In present work, microemulsion organogel from cetyltrimethylammonium bromide reverse microemulsion and gelatin was prepared and used as immobilization matrix for horseradish peroxidase (HRP, E.C.1.11.1.7). The material was further hardened with silica to enhance aqueous solution stability. The composite material was studied for enzymatic kinetics and oxidation of chlorophenols and employed as catalyst in the presence of hydrogen peroxide to oxidize 2-chlorophenol (2-CP), 2,4-dichlorophenol (2,4 - DCP), and 2,4,6-trichlorophenol (2,4,6-TCP) in an aqueous media. It was worth noting that phenols get converted to organic acids rather than typical polymerized products. The protective effect of composite material was observed which render the polymerization reaction of phenols. Michaeles-Menten constant and activity of enzyme in free and immobilized system were evaluated using three modified Michaeles-Menten equations and progressive curve experiments, respectively. The immobilized HRP followed Michaeles-Menten kinetics with lower reaction velocity constant (V_max) and Michealis constant (K_m) values comparable to free HRP. Further, following parameters were optimized: contact time, pH, hydrogen peroxide concentration, enzyme dose and analyte concentration. Under different optimized condition, the oxidative removal of phenol and their derivatives reaches up to 95-99% in phosphate buffer.